SM29氧化還原電極SM29-AG8傳感器
SM29 Redox Electrodes
Redox measurements are a potentiometrical measurement of the oxidizing/reducing power of a liquid. To be able to measure this equilibrium of reversible redox reactions the electrodes used should be inert. Noble electrodes such as Platinum (Pt) and Gold (Au) are widely used for this purpose and seem to approximate the behaviour of an ideal inert electrode. Platinum is used most widely, has excellent chemical resistance but suffers slightly from chemosorption of Oxygen, which slows down its response.
The potential of reference electrodes is depending on their
composition. A table with the actual values for each system is given next. All values refer to 25°C. The reference system is also indicated on the textplate of the electrode.
System | Fill solution | Value against Standard Hydrogen Electrode |
Ag/AgCl | 3.3 m. KCl | 203 mV |
Ag/AgCl | sat. KCl | 196 mV |
Combined Redox Electrodes
For redox measurement Yokogawa offers non-flow general purpose electrodes and a heavy duty flow electrode. All electrodes are equiped with a solid platinum pin to provide long
lifetime, even in processes that harm the platinum electrodes such as hypochloride.
METAL ELECTRODES
l Polarisation free measurement by (patented) inert metal surface.
l Dome shaped cup
l Temperature range 0…130°C
l Steam sterilisable.
l Maximum process pressure: 1 MPa (10 bar)
The Redox (ORP) electrode can be used in combination with all
reference electrodes in the program of Yokogawa.
The potential of reference electrodes is depending on their
composition.
A table with the actual values for each system is given next. All
values refer to 25°C
System | Fitting | Absolute value | Value against SCE |
Ag/AgCl Ag/AgCl Calomel (SME) | 1 m KCl sat. KCl sat. KCl | 233 mV 188 mV 241 mV | - 8 mV - 45 mV 0 mV |
The reference system is also indicated on the textplate of the electrode
TYPE | TEMP. RANGE | PROCESS PRESSURE | METAL SURFACE |
SM29-AG8 SM29-AU8 SM29-PT9 | 0…130°C 0…130°C 0…130°C | maximum 1 MPa (10 bar) maximum 1 MPa (10 bar) maximum 1 MPa (10 bar) | silver gold solid platinum |
pH電極又稱pH探頭、pH傳感器,英文名稱pH electrode或pH sensor,是PH計上與被測物質(zhì)接觸的部分,用來測電極電位的裝置。
通常有兩種方法測量水相溶液中的pH值,比色法(pH試紙和比色皿)和電位法。電位法是能夠?qū)崿F(xiàn)連續(xù)在線測量和過程監(jiān)控的*方法,而且電位法可獲得精確且結(jié)果可重復的pH值,pH電極測量的核心理論是能斯特方程。
電位分析法所用的電極被稱為原電池。原電池是一個系統(tǒng),它的作用是使化學反應(yīng)能量轉(zhuǎn)成為電能。此電池的電壓被稱為電動勢(EMF)。此電動勢(EMF)由二個半電池構(gòu)成。其中一個半電池稱作測量電極,它的電位與特定的離子活度有關(guān);另一個半電池為參比半電池,通常稱作參比電極,它一般是與測量溶液相通,并且與測量儀表相連。zui熟悉也是zui常用的PH指示電極是玻璃電極。
一套工業(yè)在線pH測量系統(tǒng)通常由pH傳感器即pH電極、pH變送器、電極護套及電纜等四部分構(gòu)成。
zui初人們對酸堿的意識是入口食物的味道,譬如醋是酸的,檸檬也是酸的,嘗起來澀澀的堿面是堿性的,這是pH值或酸堿度zui初的由來,簡單直觀。
以摩爾值表示水相溶液中的氫離子濃度,濃度從100(1)到10-14,再以10為底的負對數(shù)換算,pH范圍即為0-14。pH是拉丁文pondus hydrogenii的縮寫,pondus =壓強,hydrogenii =氫。因此,更精準的pH值定義應(yīng)是水相溶液中氫離子活度的負對數(shù)值,理解這一點非常重要。您可以因此了解到*: 相對而言,液體更容易實現(xiàn)精確的pH值測量,第二: 水相溶液環(huán)境里更容易實現(xiàn)精確的pH值測量。
而且,日常生活工作和生產(chǎn)中大部分的pH[1]值測量都是圍繞液體工作的。例如人類攝入的食物藥物以及液體居多,即使終產(chǎn)品不是液體其來源環(huán)境也是液體,譬如人類的液體食物有很多:白酒、啤酒、碳酸飲料、果汁、咖啡和茶葉,pH值影響著食物的風味和品質(zhì),pH值是藥物生產(chǎn)中的重要指標。而pH值檢測并不簡單,工業(yè)制藥生產(chǎn)液態(tài)物質(zhì)比固態(tài)物質(zhì)多得多(由此不難理解工業(yè)上水的重要性了),常見工業(yè)用水有冷卻水、清洗用水、加熱水、蒸汽和溶劑用水等,除此之外,還包括需要進一步做環(huán)保處理的污水。那么,工業(yè)生產(chǎn)中,物質(zhì)經(jīng)歷著各種變化,相當一部分反應(yīng)又伴隨著氫離子濃度的變化,因此檢測水相溶液中氫離子濃度的大小即pH值尤為重要。
精確的pH測量可以幫助實現(xiàn):
1、生產(chǎn)出我們預期想要的產(chǎn)品
2、盡可能的以*生產(chǎn)
3、防止物料損壞、人員傷亡和環(huán)境污染
4、滿足法規(guī)要求
5、研發(fā)工作順利進行